Evidence of the Zn vacancy acting as the dominant acceptor in n-type ZnO.

نویسندگان

  • F Tuomisto
  • V Ranki
  • K Saarinen
  • D C Look
چکیده

We have used positron annihilation spectroscopy to determine the nature and the concentrations of the open volume defects in as-grown and electron irradiated (E(el)=2 MeV, fluence 6 x 10(17) cm(-2)) ZnO samples. The Zn vacancies are identified at concentrations of [V(Zn)] approximately 2 x 10(15) cm(-3) in the as-grown material and [V(Zn)] approximately 2 x 10(16) cm(-3) in the irradiated ZnO. These concentrations are in very good agreement with the total acceptor density determined by temperature dependent Hall experiments. Thus, the Zn vacancies are dominant acceptors in both as-grown and irradiated ZnO.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Evidence for native-defect donors in n-type ZnO.

Recent theory has found that native defects such as the O vacancy V(O) and Zn interstitial Zn(I) have high formation energies in n-type ZnO and, thus, are not important donors, especially in comparison to impurities such as H. In contrast, we use both theory and experiment to show that, under N ambient, the complex Zn(I)-N(O) is a stronger candidate than H or any other known impurity for a 30 m...

متن کامل

Point defects in ZnO: an approach from first principles.

Recent first-principles studies of point defects in ZnO are reviewed with a focus on native defects. Key properties of defects, such as formation energies, donor and acceptor levels, optical transition energies, migration energies and atomic and electronic structure, have been evaluated using various approaches including the local density approximation (LDA) and generalized gradient approximati...

متن کامل

Formation of isolated Zn vacancies in ZnO single crystals by absorption of ultraviolet radiation: a combined study using positron annihilation, photoluminescence, and mass spectroscopy.

Positron annihilation spectra reveal isolated zinc vacancy (V(Zn)) creation in single-crystal ZnO exposed to 193-nm radiation at 100 mJ/cm(2) fluence. The appearance of a photoluminescence excitation peak at 3.18 eV in irradiated ZnO is attributed to an electronic transition from the V(Zn) acceptor level at ~100 meV to the conduction band. The observed V(Zn) density profile and hyperthermal Zn(...

متن کامل

Ga-related photoluminescence lines in Ga-doped ZnO grown by plasma-assisted molecular-beam epitaxy

Low-temperature photoluminescence PL and temperature-dependent Hall-effect T-Hall measurements were carried out in undoped and Ga-doped ZnO thin films grown by molecular-beam epitaxy. As the carrier concentration increases from 1.8 1018 to 1.8 1020 cm−3, the dominant PL line at 9 K changes from I1 3.368–3.371 eV to IDA 3.317–3.321 eV , and finally to I8 3.359 eV . The dominance of I1, due to io...

متن کامل

The Zn-vacancy related green luminescence and donor–acceptor pair emission in ZnO grown by pulsed laser deposition

A low temperature (10 K) photoluminescence study shows that green luminescence (GL) peaking at 2.47 eV and near band edge (NBE) emission at 3.23 eV are introduced in undoped ZnO grown by pulsed laser deposition (PLD) after 900 C annealing. The NBE emission exhibiting blue shift with increasing temperature is assigned to the transitions of the donor–acceptor-pair (DAP)/free-electron-to-acceptor ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Physical review letters

دوره 91 20  شماره 

صفحات  -

تاریخ انتشار 2003